Are you sure you're not mixing it up with split complimentary or something?
http://www.writedesignonline.com/res...les/color.html
And I'm sorry if I sound snarky, but the clear definition to complementary colours (two colours opposite of the colour wheel) is easy to find from Wikipedia and everywhere else if you just bother to look.
EDIT:
"The complement of each primary color (red, blue, or yellow) is roughly the color made by mixing the other two in a subtractive system"
Is that what you meant? Well, that's basically just harder way to say "opposite in colour wheel". It's easier to just take a colour wheel and look at the opposites.

Blue-violet is the complementary of yellow-orange.
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